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Define the following terms: 1.1 homologous series 1.2 functional group write down the structural formula of the functional group for the following homologous series: 2.1 alcohols 2.2 aldehydes 2.3 carboxylic acids 2.4

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Jan 23,2025

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**Definitions:** 1. **Homologous Series:** A group of organic compounds with the same general formula, similar properties, and increasing molecular size by a specific structural unit (e.g., alkanes: methane, ethane, propane). 2. **Functional Group:** A specific group of atoms within a molecule responsible for the characteristic chemical reactions of that molecule (e.g., hydroxyl group in alcohols, carbonyl group in aldehydes). **Structural Formulas:** - **Alcohols:** R–OH - **Aldehydes:** R–CHO - **Carboxylic Acids:** R–COOH

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Certainly! Here's a detailed explanation of the requested terms and their corresponding structural formulas: --- ### **1. Definitions** #### **1.1 Homologous Series** A **homologous series** is a group of organic compounds that share the same general formula, exhibit similar chemical properties, and show a gradual change in physical properties (such as boiling point and melting point) as the molecular size increases. Each successive member of the series differs from the previous one by a specific structural unit, typically a **—CH₂—** (methylene) group. * **Example:** In the alkane series, methane (CH₄), ethane (C₂H₆), propane (C₃H₈), etc., form a homologous series where each successive molecule has one more **—CH₂—** unit than the previous one. #### **1.2 Functional Group** A **functional group** is a specific group of atoms within a molecule that is responsible for the characteristic chemical reactions of that molecule. Functional groups determine the class of organic compounds and provide sites for chemical transformations. * **Examples of Functional Groups:** - **Hydroxyl Group (–OH)** in alcohols - **Carbonyl Group (C=O)** in ketones and aldehydes - **Carboxyl Group (–COOH)** in carboxylic acids --- ### **2. Structural Formulas of Functional Groups** Below are the structural formulas for the functional groups of the specified homologous series: #### **2.1 Alcohols** - **Functional Group:** Hydroxyl Group (**–OH**) - **Structural Formula:** ``` H | R—C—OH | H ``` - **Simplified Representation:** **R–OH** Here, **R** represents an alkyl group (a chain of carbon atoms). The hydroxyl group (**–OH**) is attached to the carbon atom, making the compound an alcohol. - **Example:** Ethanol (CH₃CH₂OH) ``` H H | | H—C—C—OH | | H H ``` #### **2.2 Aldehydes** - **Functional Group:** Carbonyl Group with a Hydrogen (**–CHO**) - **Structural Formula:** ``` O || R—C—H ``` - **Simplified Representation:** **R–CHO** The carbonyl group (**C=O**) is bonded to a hydrogen atom and an alkyl group (**R**), characterizing aldehydes. - **Example:** Formaldehyde (H₂C=O) ``` H | H—C=O | H ``` #### **2.3 Carboxylic Acids** - **Functional Group:** Carboxyl Group (**–COOH**) - **Structural Formula:** ``` O || R—C—OH ``` - **Simplified Representation:** **R–COOH** The carboxyl group consists of a carbonyl group (**C=O**) bonded to a hydroxyl group (**–OH**). This functional group is responsible for the acidic properties of carboxylic acids. - **Example:** Acetic Acid (CH₃COOH) ``` H | H—C—C—OH | O || O ``` --- ### **Summary Table** | **Homologous Series** | **Functional Group** | **Structural Formula** | |-----------------------|----------------------|------------------------| | **Alcohols** | Hydroxyl (–OH) | R–OH | | **Aldehydes** | Formyl (–CHO) | R–CHO | | **Carboxylic Acids** | Carboxyl (–COOH) | R–COOH | *Where **R** represents an alkyl group (a chain of carbon atoms).* --- If you have any further questions or need more examples, feel free to ask!

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Homologous series refers to a group of organic compounds that share a similar structural feature and exhibit a gradual change in physical properties. Each member of the series differs from the next by a specific number of carbon and hydrogen atoms, typically by a -CH₂- group. This consistency allows for predicting trends in behavior, solubility, and reactivity among the series members—think of it as a family of compounds with a common heritage! Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those compounds. They essentially dictate how a compound interacts with others, making them vital in distinguishing between different classes of organic compounds. For example, the hydroxyl group (-OH) defines alcohols and the carbonyl group (C=O) is what makes aldehydes unique. Understanding functional groups helps chemists unlock the secrets of molecular behavior! The structural formula for alcohols includes the hydroxyl group (-OH), for aldehydes it’s the carbonyl group (C=O) with a hydrogen atom attached (R-CHO), and for carboxylic acids it’s the carboxyl group (-COOH).

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