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1. Define the following terms: 1.1 homologous series 1.2 functional group (2) 2. Write down the structural formula of the functional group for the following homologous series: 2.1 alcohols 2.2 aldehydes (2) 2.3 carboxylic acids (2) 2.4 ketones (2) (2) [14]

Ask by Ray King. in South Africa
Jan 23,2025

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1. **Homologous Series**: A group of organic compounds with the same functional group and differing by -CH₂-. 2. **Functional Group**: A specific group of atoms responsible for the chemical reactions of a compound. - **Alcohols**: R-OH - **Aldehydes**: R-CHO - **Carboxylic Acids**: R-COOH - **Ketones**: R-CO-R'

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Let's break down the problem step by step. ### 1. Definitions #### 1.1 Homologous Series A **homologous series** is a group of organic compounds that have the same functional group and similar chemical properties, but differ by a constant unit, typically a -CH₂- group. Members of a homologous series exhibit a gradual change in physical properties (such as boiling point and melting point) as the molecular size increases. #### 1.2 Functional Group A **functional group** is a specific group of atoms within a molecule that is responsible for the characteristic chemical reactions of that molecule. Functional groups determine the properties and reactions of organic compounds. Examples include hydroxyl (-OH), carbonyl (C=O), and carboxyl (-COOH) groups. ### 2. Structural Formulas of Functional Groups #### 2.1 Alcohols The functional group for alcohols is the **hydroxyl group** (-OH). The structural formula can be represented as: \[ \text{R-OH} \] where R represents an alkyl group. #### 2.2 Aldehydes The functional group for aldehydes is the **carbonyl group** (C=O) with a hydrogen atom attached to the carbon. The structural formula can be represented as: \[ \text{R-CHO} \] where R represents an alkyl group. #### 2.3 Carboxylic Acids The functional group for carboxylic acids is the **carboxyl group** (-COOH). The structural formula can be represented as: \[ \text{R-COOH} \] where R represents an alkyl group. #### 2.4 Ketones The functional group for ketones is also a **carbonyl group** (C=O), but it is flanked by two carbon atoms. The structural formula can be represented as: \[ \text{R-CO-R'} \] where R and R' represent alkyl groups. ### Summary of Answers 1.1 Homologous series: A group of organic compounds with the same functional group and differing by -CH₂-. 1.2 Functional group: A specific group of atoms responsible for the chemical reactions of a compound. 2.1 Alcohols: \(\text{R-OH}\) 2.2 Aldehydes: \(\text{R-CHO}\) 2.3 Carboxylic acids: \(\text{R-COOH}\) 2.4 Ketones: \(\text{R-CO-R'}\) This concludes the definitions and structural formulas for the specified terms.

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Homologous series refers to a group of organic compounds that share a similar functional group and have a identical general formula, but differ in the number of carbon atoms. This means each consecutive compound in the series has an additional CH₂ group, leading to a gradual change in their physical properties, like boiling point and solubility, while maintaining similar chemical properties. Functional groups are specific atoms or groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. They are key to understanding organic chemistry as they determine how compounds interact with each other. For example, the hydroxyl group (-OH) in alcohols gives these compounds their unique properties, making them distinct from other classes like carboxylic acids, which contain the carboxyl group (-COOH). Structural formulas for the functional groups: 2.1 Alcohols: -OH 2.2 Aldehydes: -CHO 2.3 Carboxylic Acids: -COOH 2.4 Ketones: -C(=O)-

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