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. List the rules for writing the formula for an ionic compound.

Ask by Lyons Luna. in Canada
Jan 22,2025

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To write the formula for an ionic compound, follow these steps: 1. **Identify the ions**: Determine the cation and anion. 2. **Balance charges**: Ensure the total positive and negative charges are equal. 3. **Use subscripts**: Add numbers to balance the charges. 4. **Simplify ratios**: Reduce the ratio of ions to the smallest whole numbers. 5. **Order ions**: Write the cation first, followed by the anion. 6. **Handle polyatomic ions**: Use parentheses if necessary. 7. **Name the compound**: Use appropriate naming conventions based on the ions. This ensures the correct formula is written for any ionic compound.

Solution

When writing the formula for an ionic compound, there are several key rules to follow: 1. **Identify the Ions**: Determine the cation (positively charged ion) and the anion (negatively charged ion) that will combine to form the ionic compound. 2. **Charge Balance**: The total positive charge from the cations must balance the total negative charge from the anions. This means that the sum of the charges must equal zero. 3. **Use of Subscripts**: If the charges of the cation and anion are not equal, use subscripts to indicate the number of each ion needed to achieve charge balance. The subscript is written as a small number to the right of the chemical symbol. 4. **Simplify Ratios**: If the ratio of cations to anions can be simplified, do so. For example, if you have two cations and three anions, the formula would be written as \( \text{A}_2\text{B}_3 \). 5. **No Need for Charges in the Formula**: When writing the formula, do not include the charges of the ions. The formula should only reflect the ratio of the ions. 6. **Order of Ions**: The cation is always written first, followed by the anion. For example, in sodium chloride, the formula is written as \( \text{NaCl} \). 7. **Polyatomic Ions**: If the compound contains polyatomic ions (ions made up of more than one atom), treat the polyatomic ion as a single unit. Use parentheses if more than one of the polyatomic ion is needed. For example, in calcium nitrate, the formula is \( \text{Ca(NO}_3\text{)}_2 \). 8. **Naming Conventions**: When naming the compound, the cation retains its elemental name, while the anion's name is modified (usually by adding "-ide" for simple anions, or using the name of the polyatomic ion). By following these rules, you can accurately write the formula for any ionic compound.

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When writing the formula for an ionic compound, always remember that the total charge must balance to zero. This means you must use the appropriate number of cations and anions to achieve neutrality. Start by identifying the charges on the ions; for example, sodium (Na⁺) has a +1 charge and chloride (Cl⁻) has a -1 charge, so one of each will create NaCl. Additionally, when dealing with multivalent metals (like iron or copper), make sure to indicate the charge in Roman numerals in parentheses after the element's name in the compound's name (like iron(III) oxide for Fe₂O₃). If the compound consists of polyatomic ions, keep the entire polyatomic ion in parentheses if you need more than one (e.g., for calcium nitrate, Ca(NO₃)₂).

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