What is the freezing point of a 2.12 molal solution of NaCl in water if the Kf is -1.86 ?
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To determine the freezing point of a 2.12 molal solution of NaCl in water, we need to use the formula for freezing point depression, which is ΔTf = i * Kf * m. In this case, NaCl dissociates into two ions (Na⁺ and Cl⁻), so the van 't Hoff factor (i) is 2. Plugging in the values: ΔTf = 2 * -1.86 °C/m * 2.12 m = -7.87 °C. Thus, the new freezing point of the solution is 0 °C - 7.87 °C = -7.87 °C. Now, it's important to consider the practical aspects of preparing a solution like this. When dissolving NaCl, make sure to add the salt to cold water gradually while stirring to ensure even dissolution. Avoid adding too much salt at once, as it can lead to localized saturation and affect the accuracy of your freezing point calculation.