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What is the freezing point of a 2.12 molal solution of NaCl in water if the Kf is -1.86 ?

Ask by Summers Mitchell. in the United States
Jan 24,2025

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Answer

The freezing point of the 2.12 molal NaCl solution is approximately –7.9 °C.

Solution

To determine the freezing point of a 2.12 molal (m) solution of NaCl in water, we use the freezing point depression formula: \[ \Delta T_f = i \times K_f \times m \] Where: - \(\Delta T_f\) = change in freezing point - \(i\) = van 't Hoff factor (number of particles the solute dissociates into) - \(K_f\) = cryoscopic constant (freezing point depression constant) - \(m\) = molality of the solution **Given:** - \(m = 2.12\) mol/kg - \(K_f = 1.86\) °C·kg/mol (Note: Freezing point depression constants are typically positive, even if the question provides a negative value, because the formula accounts for the depression itself.) - For NaCl, \(i = 2\) (since NaCl dissociates into Na\(^+\) and Cl\(^-\)) **Calculation:** \[ \Delta T_f = 2 \times 1.86 \times 2.12 = 7.89 \text{ °C} \] This means the freezing point is lowered by 7.89°C from that of pure water. **Final Freezing Point:** \[ \text{Freezing point} = 0°C - 7.89°C = -7.89°C \] **Rounded to one decimal place:** \[ \text{Freezing point} \approx -7.9°C \] **Answer:** The solution freezes at approximately –7.9 °C.

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To determine the freezing point of a 2.12 molal solution of NaCl in water, we need to use the formula for freezing point depression, which is ΔTf = i * Kf * m. In this case, NaCl dissociates into two ions (Na⁺ and Cl⁻), so the van 't Hoff factor (i) is 2. Plugging in the values: ΔTf = 2 * -1.86 °C/m * 2.12 m = -7.87 °C. Thus, the new freezing point of the solution is 0 °C - 7.87 °C = -7.87 °C. Now, it's important to consider the practical aspects of preparing a solution like this. When dissolving NaCl, make sure to add the salt to cold water gradually while stirring to ensure even dissolution. Avoid adding too much salt at once, as it can lead to localized saturation and affect the accuracy of your freezing point calculation.

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