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CHM 111: General Chemistry 1 2024/2025 Session INSTRUCTION: Answer all questions Question \# 1 An antacid tablet contains sodium hydrogen carbonate, NaHCO3, and inert ingredient. A 0.500 g sample of powdered tablet was mixed with 50.0 mL of 0.190 M HCl (hydrochloric acid). The mixture was allowed to stand until it reacted. NaHCO3(s)+HCl(aq)NaCl(aq)+H2O(l)+CO2(g) The excess hydrochloric acid was titrated with 47.1 mL of 0.128 M NaOH (sodium hydroxide). HCl(aq)+NaOH(aq)NaCl(aq)+H2O(l) What is the percentage of sodium hydrogen carbonate in the antacid? Question \# 2 Arsenic acid, H3AsO4, is a poisonous acid that has been used in the treatment of wood to prevent insect damage. Arsenic acid has three acidic protons. Say you take a 26.14mL sample of arsenic acid and prepare it for titration with NaOH by adding 25.00 mL of water. The complete neutralization of this solution requires the addition of 53.07 mL of 0.6441 M NaOH solution. Write the balanced chemical reaction for the titration, and calculate the molarity of the arsenic acid sample. Question \# 3 Arrange the following substances ( 1 mole each) in order of increasing entropy at 25C. (a) Ne(g). (b) SO2(g), (c) Na(s),, (d) NaCl(s),, (e) H2(g).. Give the reasons for your arrangement. Question \# 4 State whether the sign of the entropy change expected for each of the following processes will be positive or negative, and explain your predictions. (a) PCl3(l)+Cl2(g)PCl5(s) (b) 2HgO(s)2Hg(l)+O2(g) (c) H2(g)2H(g) (d) U(s)+3 F2( g)UF6(s)
Chemistry Mar 28, 2025
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