Question
upstudy study bank question image url

Draw resonance structures for , showing the delocalization of charge using
curved arrows.
QUESTION 6
Calculate the amount of sed um hydroxide that is needec-to prepare one itre of a
350 molar sodium hydroride solution.

Ask by Graham Gibson. in South Africa
Jan 21,2025

Upstudy AI Solution

Tutor-Verified Answer

Answer

To prepare 1 litre of a 0.350 M sodium hydroxide (NaOH) solution, you need 14.00 grams of solid NaOH.

Solution

Certainly! Let’s address both parts of your query:
  1. Resonance Structures for
  2. Calculation of Sodium Hydroxide Needed for a Sodium Hydroxide Solution

1. Resonance Structures for

Assuming you’re referring to the carbonate ion ( ), it exhibits resonance due to the delocalization of electrons. The carbonate ion has three equivalent resonance structures where the double bond between carbon and oxygen is rotated among the three oxygen atoms.
Structure Description:
  • Central Atom: Carbon ©
  • Surrounding Atoms: Three oxygen (O) atoms
  • Charge Distribution: Each oxygen carries a -1/3 charge on average in resonance.
Resonance Structures:
  1. Structure 1:
    • Double bond between C and one O.
    • Single bonds between C and the other two O atoms.
    • Negative charges on the two single-bonded O atoms.
  2. Structure 2:
    • Double bond between C and a different O.
    • Single bonds between C and the remaining two O atoms.
    • Negative charges on the two single-bonded O atoms.
  3. Structure 3:
    • Double bond between C and the third O.
    • Single bonds between C and the other two O atoms.
    • Negative charges on the two single-bonded O atoms.
Curved Arrow Representation:
  • Electron Movement: The π electrons from the double bond shift to form a double bond with another oxygen, while the single bond electrons shift to accommodate the resonance.
    O⁻        O        O⁻
     \\        |        /
      C  <-->  C  <-->  C
     /          \\        \
    O⁻           O        O⁻
    
Due to text limitations, visual representation using curved arrows isn’t feasible here. However, each resonance structure can be visualized by moving the double bond and the lone pair electrons among the oxygen atoms in a cyclic manner.

2. Calculating the Amount of Sodium Hydroxide Needed

Problem Statement:
Calculate the amount of solid sodium hydroxide (NaOH) needed to prepare one litre of a 350 molar (M) sodium hydroxide solution.
However, there’s a consideration to be made:
  • A 350 M solution of NaOH is physically impossible because it exceeds the solubility of NaOH in water. Typically, the maximum solubility of NaOH in water at room temperature is about 111 g per 100 mL, which corresponds to approximately 27.6 M.
Assuming there might be a typo and the intended concentration is 0.350 M, here’s how to perform the calculation:

Revised Problem Statement:
Calculate the amount of solid sodium hydroxide (NaOH) needed to prepare one litre of a 0.350 molar (M) sodium hydroxide solution.
Step-by-Step Calculation:
  1. Understand Molarity (M):
  2. Given:
    • Desired Molarity ( ) = 0.350 M
    • Volume ( ) = 1 litre
  3. Calculate Moles of NaOH Needed:
  4. Determine Molar Mass of NaOH:
    • Sodium (Na) = 22.99 g/mol
    • Oxygen (O) = 16.00 g/mol
    • Hydrogen (H) = 1.01 g/mol
  5. Calculate Mass of NaOH Needed:
Conclusion:
To prepare 1 litre of a 0.350 M sodium hydroxide solution, you would need 14.00 grams of solid NaOH.

Final Note:
Please verify the intended concentration for the sodium hydroxide solution. If 350 M was indeed your intended concentration, it would not be feasible due to solubility limitations. For practical laboratory preparations, concentrations are typically kept well below this value.

Answered by UpStudy AI and reviewed by a Professional Tutor

error msg
Explain
Simplify this solution

Beyond the Answer

To draw the resonance structures for (carbonate ion), you can start with one structure where the carbon is double-bonded to one oxygen and single-bonded to the other two oxygens, which each carry a negative charge. Then, you create two additional resonance structures by shifting the double bond between carbon and an oxygen in the direction of one of the negatively charged oxygens. Use curved arrows to show the movement of electrons during this process, highlighting the delocalization of the negative charge across the oxygen atoms.
To prepare a 350 M solution of sodium hydride ( ), you need to calculate the necessary amount of sodium hydroxide ( ) since they are equivalently reacting species. A 350 M solution means you need 350 moles of sodium hydroxide in one liter. Given that has a molar mass of about 40 g/mol, you would need 350 moles × 40 g/mol = 14,000 g of sodium hydroxide to make one liter of this highly concentrated solution. Quite a hefty amount, so definitely handle with care!

Related Questions

Latest Chemistry Questions

Try Premium now!
Try Premium and ask Thoth AI unlimited math questions now!
Maybe later Go Premium
Study can be a real struggle
Why not UpStudy it?
Select your plan below
Premium

You can enjoy

Start now
  • Step-by-step explanations
  • 24/7 expert live tutors
  • Unlimited number of questions
  • No interruptions
  • Full access to Answer and Solution
  • Full Access to PDF Chat, UpStudy Chat, Browsing Chat
Basic

Totally free but limited

  • Limited Solution
Welcome to UpStudy!
Please sign in to continue the Thoth AI Chat journey
Continue with Email
Or continue with
By clicking “Sign in”, you agree to our Terms of Use & Privacy Policy